に加えて・のみならず・おまけに: the difference
に加えてN2
Meaning
Not only...but also, In addition, Not to mention
Past papers
Example
今学期から文法に加えて漢字も教えることになった。
Starting this semester, in addition to grammar, I will also be teaching Kanji.
のみならずN2
Meaning
Not only...but, Not just...but, What is more
Past papers
Tested 2 times in past papers
Example
炭素繊維は極めて丈夫であるのみならず非常に軽いらしい。
Apparently, carbon fiber is not only extremely durable, but also very light.
おまけにN2
Meaning
In addition, On top of that, What is more, To make matters worse
Past papers
Example
家を掃除した。御負けにランチを作っといた。
I cleaned the house. On top of that, I also made lunch.
How to tell them apart
「に加えて」: adds a new fact onto an existing one; common in writing and news.
「のみならず」: 'not only A but B too'; the tone of an essay.
「おまけに」: casual; starts a sentence to add one more thing.